See Greek Accents for an overview.

The forms which begin with vowel (ὁ, ἡ, οἱ, αἱ) are proclitics.

All other nominative and accusative forms are oxytone.

All genitive and dative forms are perispomenon.

NumCaseMascFemNeut
SgNomτό
Accτόντήντό
Genτοῦτῆςτοῦ
Datτῷτῇτῷ
PlNomοἱαἱτά
Accτούςτάςτά
Genτῶντῶντῶν
Datτοῖςταῖςτοῖς

These rules also hold for the dual:

NumCaseMascFemNeut
DlNom/Accτώτώτώ
Gen/Datτοῖντοῖντοῖν